Materials & Surfaces
WHAT ARE FUNCTIONAL SURFACES?
Function arises at the boundary of two phases.
A functional surface is a boundary layer whose properties are specifically adjusted in order to create a technical effect, repel water, reduce friction, regulate heat, inhibit bacteria.
The decisive realisation of the last 30 years: geometry has a stronger effect than chemistry. Structures in the micro- and nanometer range already fundamentally change wetting behaviour, optical properties and adhesion without the material itself having to be replaced.
Materials science and surface technology work on three scales: macroscopic (form), microscopic (topography) and nanoscopic (molecule arrangement). Each scale addresses different physical phenomena.
“What happens on a surface decides whether a material works, not what it is.”
AT A GLANCE
Discipline
Surface Physics & Materials Science
SCALES
cm → nm
Six orders of magnitude relevant
KEY MODELS
Wenzel · Cassie-Baxter
wetting, 1936/1944
PHENOMENA
Hydrophobia · Tribology · Adhesion · Structure colour
MEASURING VARIABLES
Contact angle · Ra · COF
Standard parameters of functional surfaces
BASIC PRINCIPLES
Four laws that characterise any functional surface.
Those who develop surfaces work with physical rules, not with coating formulations. These four principles are the workbench.
Geometry beats chemistry
A pure polymer surface becomes superhydrophobic by structuring, without fluorine-containing additives. Mould acts before fabric.
Scale determines effect
Friction, wetting and colour are created on its own scale. Those who micro-structure do not necessarily influence the visual impression.
Function is measurable
Contact angle, coefficient of friction, adhesion force, each function has an established measuring variable. “Effects” does not apply.
Hierarchies have a stronger effect
Natural models combine several scales at the same time. A single structural layer rarely achieves the same robustness.
HOW DOES THE METHOD WORK?
Scales of a functional surface.
Materials science does not address “the surface”, but a hierarchy of interlocking scales. Each scale has its own effects and production processes.
Macro form
Component geometry · Flow routeing · Curvatures
Riblets & Textures
Flow grooves · gripping structures · tactile fields
Micro-topography
Pillars · Pits · Gradients · Wetting Control
Nano-structures
Anti-reflection · Photonic crystals · Structure colour
Molecular layer
SAMs · Coating chemistry · Functionalisation
EXAMPLES FROM NATURE
Where structures work, where substance alone fails.
Three surfaces that show well why materials science has become geometry science today.

Lotus effect
Micropapilles plus nanowax create a contact angle > 150°. Water beads off and takes particles with it. Chemically, the leaf is not particularly water-repellent.
Effect · Superhydrophobia · Scale · µm + nm

Morpho-Both
The bright blue is created without pigment, by interference on stacked nanolamelles. The same colour without dye, without fading.
Effect · Interference · Scale · nm

Mother-of-pearl
95% brittle lime, 5% proteins and 3000 times fracture resistance compared to the pure material. A wall geometry that deflects any crack reproduction.
Effect · Hierarchical network · Scale · µm + nm
STANDARDS & FURTHER SOURCES
On what basis we work.
NORM
DIN EN ISO 4287 / 4288
Geometric product specification — surface texture, tactile cutting.
MODEL
Wenzel (1936) · Cassie-Baxter (1944)
Classic models for describing the wetting of textured surfaces.
Research
Barthlott & Neinhuis (1997)
First publication of the lotus effect, Planta 202.
NORM
DIN EN ISO 25178
Surface characterisation — 3D topography of functional surfaces.
Book
Bhushan, B.: Biomimetics — Bioinspired Surfaces
Springer, 2016. Reference work on the microstructure of functional surfaces.
Association
DGM — German Society of Materials Science
Specialist committees on surface technology and functional materials.
Contact
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